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Material Safety Data Sheet

Gordon's Permasil #909C Carnauba Wax Mold Release
(Green Label)



Section 1: PRODUCT AND COMPANY IDENTIFICATION

  A. Common Name:
(Trade Name & Synonyms)

GORDON'S PERMASIL #909 "C" (Green Label) 100% Non-Ozone
Depleting Aerosol carnauba Was Mold Release Spray

  B. Manufacturer's Name:   M.J. Gordon Company
  C. Address:   P.O. BOX 4441; PITTSFIELD, MASSACHUSETT 01202-4441
  D. 24 HOUR EMERGENCY TELEPHONE NUMBERS:   C H E M T R E C
Outside of the U.S. (703) 527-3887
Within the U.S. (800) 424-9300
  E. CORPORATE CONTACT NUMBERS:  

Phones: (413) 448-6066 or (888) 463-1044
Fax: (413) 448-2932

  F. NAME OF PERSON RESPONSIBLE FOR PREPARATION:  

Allan B. Gordon, President

  F. DATE PREPARED:  

January 01, 2007


Section 2: PRODUCT AND COMPANY IDENTIFICATION

  A. CAS No:

See Chart Section 2

  B. Chemical Family:   Mold Release Agent.
  C. Formula:   Yes.
  D. Hazardous Ingredients (Principal Hazardous Components):
Chemical and
Common Names		 CAS # OSHA
PEL		 AGCIH
TLV		 Vapor Pressure
at 250° C		 LEL UEL Flash
Pt. °F
n-Propyl bromide 106-94-5 Not
Established*		 Not
Established*		 111 mmHg 4.0 7.8 None
1,1,1,2- 811-97-2 N/A** N/A** 96 psia Nonflam
mable		 Nonflam
mable		 None
Dimethyl ether 115-10-6 1000 ppm 1000 ppm 71 psig 3.4 18.0 -42 (T0C)
Xylenes*** 1330-20-7 100 ppm 100 ppm 10 mmHg 1.0 7.0 80 (TCC)
NOTE: Refer to Section 8 for content breakdown and SARA TITLE III information.

Section 3: HAZARDS IDENTIFICATION

A. PHYSICAL HAZARDS:

 

    1. Stability:

Stable.

    2. Conditions to Avoid:  

Avoid any ignition source. Avoid excessive heat. ignition sources, open flames, or other high temperatures which induce thermal decomposition.

    3. Incompatibility
(Materials to Avoid):		  

Strong Oxidizers, Strong Bases.

    4. Hazardous Decomposition Products:  

Hydrogen Bromide, carbon Dioxide, Carbon Monoxide.See Section 3-B-2 - HEALTH HAZARDS for Signs and Symptoms of Exposure.

    5. Hazardous Polymerization:  

Will not occur.

    6. Unusual Fire and Explosion Hazards:  

Contents under pressure. Self-pressurized aerosol containers. Keep temperature of containers below 120°F to prevent bursting.Although aerosols are classified as nonflammable under ASTMD 3065-77 Flame Projection Test, this product should not be used nor stored near any open flames or ignition sources. Hazardous decomposition products.

B HEALTH HAZARDS:  

 

    1. Threshold Limit value:   See Section 2

    2. Signs and Symptoms of Exposure:  

EYE CONTACT: Contact with liquid or mist may cause irritate eyes.

SKIN CONTACT: Prolonged contact may cause irritation, defatting of skin.

INHALATION: Overexposure to vapor may cause dizziness, loss of concentration and irritation. Repeated inhalation of high concentrations may cause lung, kidney, liver, and reproductive effects. Product vapors displace air and can cause suffocation especially in a confined space. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING CONTENTS OF THE CAN MAY BE HARMFUL OR FATAL.

INGESTION: Not expected to be a hazard in normal industrieal use. Aspiration may cause rapid absorption through the lungs, which may result in systemic effects.


IMPORTANT NOTICE: REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS MAY LEAD TO PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, AND LOSS OF COORDINATION ARE SIGNS THAT SOLVENT LEVELS ARE TOO HIGH. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING MAY BE HARMFUL OR FATAL.

  C. Chemical Listed As Carcinogen or
Potential Carcinogen:		  
  1. National Toxicology Program........NO
  2. I.A.R.C. Monographs.....................NO
  3. OSHA............................................NO
  D. OSHA Permissible Exposure Limit:   See Section 2
  E. ACGIH Threshold Limit Value:   See Section 2
  F. Other Exposure Limit Used:  

None.


Section 4: FIRST-AID MEASURES

  A. Inhalation:  

Remove to fresh air. If not breathing, give mouth-tomouth resuscitation. If breathing is difficult, give oxygen. Do not give epinephrine or similar drugs. Call a physician.

  B. Eyes:  

Flush with flowing water immediately and continuously for 15 minutes. Consult medical personnel.

  C. Skin:  

Wash off in flowing water or shower. Remove contaminated clothing and wash before reuse..

  D. Ingestion:  

Do not induce vomiting. Call a physician immediately.


Notice To Physicians: BECAUSE OF POSSIBLE DISTURBANCES OF CARDIAN RHYTHM, CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE, SHOULD ONLY BE USED WITH SPECIAL CAUTION IN SITUATIONS OF EMERGENCY LIFE SUPPORT.

  E. Symptoms:  

See Section 3B - HEALTH HAZARDS.


Section 5: FIRE FIGHTING MEASURES

A. Extinguisher Media:

Water fog, dry chemical, carbon dioxide.

  B. Special Fire Fighting Procedures:  

Water may be used to cool closed containers to prevent pressure buildup and possible bursting when exposed to high remperature. Firemen should wear self-contained, positive pressure respiratory equipment.


Section 6: ACCIDENTAL RELEASE MEASURES

  A. Small Spills:

Remove ignition sources. Mop up, wipe up, or soak up immediately. Use proper protective equipment.

  B. Large Spills:

Evacuate area. Remove ignition sources. Contain liquid; transfer to closed containers; keep out of water supplies.

  C. Waste Disposal Methods:

Dispose in accordance with Federal, State, and local regulations. Do not incinerate closed or empty containers.


Section 7: HANDLING AND STORAGE

A. HANDLING:

 

  1. Respiratory Protection:

NIOSH or Bureau of Mines approved organic vapor-type respirator is required in absence of proper environmental control.

  2. Ventilation:  
  1. Local Exhaust ...............To keep below TLV
  2. Mechanical (General)....To keep below TLV
  3. Special...........................None
  4. Other..............................None
  3. Hand Protection:  

Solvent resistant gloves; impervious gloves.

  4. Eye Protection:  

Safety Glasses or Goggles.

  5. Other Protective Clothing or Equipment:  

None reasonably foreseeable.

B. STORAGE:

Do not store above 110°F. Avoid breathing vapors. Vapors are heavier than air and will collect in low areas. Avoid prolonged or repeated contact with skin. Do not store near open flames or any other ignition source.

C. OTHE PRECAUTIONS:

Contents under pressure. Do not puncture or incinerate. Vapors are heavier than air and will collect in low areas.


Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

     

See Section 2, 3, 4 and 7


Section 9: PHYSICAL AND CHEMICAL PROPERTIES

  A. Boiling Point (°F.): Concentrate Range: 110°F - 280°F
Propellant: -16.4
  B. Specific Gravity (Water = 1):   Concentrate: 1.2
Propellant: 109.2
  C. Vapor Pressure (mm Hg):   See Section 2
  D. Percent Volatile by Volume:   100% - See Section 11-A
  E. Vapor Density (Air = 1):   >1
  F. Evaporation Rate (BA = 1):   >1
  G. Solubility in Water:  

Negligible.

  H. Reactivity in Water:  

None.

  I. Appearance and Odor:   1. CONCENTRATE: Clear, amber liquid, irritating odor at high concentrations.
2. PROPELLANT: Colorless, odorless gas.
3. FINISHED PACKAGE: Pressurized containers.
  J. Flash Point:   See Section 2
  K. Flammable in Air (% by Vol.):   See Section 2

Section 10: STABILITY AND REACTIVITY

  A. Conditions to Avoid:

See Section 3-A-2

  B. Materials to Avoid:  

See Section 3-A-3.

  C. Hazardous Decomposition
Products:		  

See Section 3-A-4.

Section 11: TOXICOLOGICAL INFORMATION

      A. Percentages of Hazardous Ingredients:
Chemical and
Common Names		 CAS # % By Weight Subject to Section 313 SARA Title III
n-Propyl bromide 106-94-5 30-40% No.
1,1,1,2- 811-97-2 20-30% No.
Dimethyl ether 115-10-6 10-20% No.
Xylenes 1330-20-7 20-30% Yes.

These chemicals are reported on teh United States Environmental Protection Agency TOXIC SUBSTANCES CONTROL ACT Inventory (TSCA).


      B. National Fire Protection Agency (NFPA) and Hazardous Material Identification System (HMIS) Ratings:
FLAMMABILITY HEALTH REACTIVITY PROTECTIVE
EQUIPMENT
NFPA 2 2 0 N/A.
HMIS 2 2 0 B

Section 12: ECOLOGICAL INFORMATION

     

In small quantities none indicated


Section 13: DISPOSAL CONSIDERATIONS

     

See Section 6-C


Section 14: TRANSPORTATION INFORMATION

DOMESTIC GROUND DOMESTIC AIR INT'L GROUND INT'L AIR OCEAN
Proper Shipping Name Consumer
Commodity		 Aerosols
non-flammable		 Consumer
Commodity		 Aerosols
non-flammable		 Aerosols
(maximum 1)
Class or Division N/A 2.2 N/A 2.2 2
UN Number N/A UN1950 N/A UN1950 UN1950
Packing Group N/A None N/A None None
Subsidiary Risk N/A None N/A None None
Hazard Label None Non-flammable
Gas 2		 None Non-flammable
Gas 2		 Non-flammable
Gas 2
Carton Marking Consumer
commodity ORM-D		 I.A.T.A
Marking		 Consumer
commodity ORM-D		 I.A.T.A
Marking		 I.A.T.A
Marking
Type of Packaging Fibreboard Box
Box 4-G		 Fibreboard
Box 4-G		 Fibreboard Box
Box 4-G		 Fibreboard
Box 4-G		 Fibreboard
Box 4-G
Packing Instruction N/A Y203 None Y203 None
Authorization N/A Ltd. QTY None Ltd. QTY None

Section 15: REGULATORY INFORMATION

     

See Section 14. Information based upon -up-to-date Regulations contained in the 49CFR; the IATA Dangerous Good Regulation (DGR),and the IMDG Code.

The M.J. Gordon Co. Believes that the information contained herein is accurate and reliable as of the date of this M.S.D.S., but no representation, guarantee, or warranty, express or implied, is made as to the accuracy, reliability, or completeness of the information. Persons receiving this information are encouraged to make their own determination as to the information's suitability and completeness for their particular application. No information contained herein constitutes a product warranty of any kind, whether express or implied; and all implied warranties of merchantability and/or fitness for a particular purpose are hereby disclaimed.

PRODUCT AND
COMPANY IDENTIFICATION

PRODUCT AND COMPANY
IDENTIFICATION

HAZARDS IDENTIFICATION

FIRST-AID MEASURES

FIRE FIGHTING MEASURES

ACCIDENTAL RELEASE
MEASURES

HANDLING AND STORAGE

EXPOSURE CONTROL/
PERSONAL PROTECTION

PHYSICAL AND CHEMICAL
PROPERTIES

STABILITY AND REACTIVITY

TOXICOLOGICAL
INFORMATION

ECOLOGICAL INFORMATION

DISPOSAL CONSIDERATIONS

TRANSPORTATION
INFORMATION

REGULATORY INFORMATION